| No. | Name | Title | Tenure |
|---|---|---|---|
| 1 | H.E. Grace A. Mgovano | High Commissioner | 2016 - 2017 |
| 2 | H.E. Dr. Ladislaus C. Komba | High Commissioner | 2011 - 2016 |
| 3 | H.E. Saleh Boi Tambwe | High Commissioner | 1996 - 2004 |
| 4 | H.E. Joshua W. Opanga | High Commissioner | 1989 - 1996 |
| 5 | H.E. Herman M. Mkwizu | High Commissioner | 1981 - 1988 |
